Synthesis and catalytic properties of arene complexes of ruthenium(II) prepared from Si, Zr, Ti and Al alkoxides by the sol-gel process

CETINKAYA B., Seckin T., Ozdemir I., Alici B.

JOURNAL OF MATERIALS CHEMISTRY, cilt.8, sa.8, ss.1835-1838, 1998 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 8 Sayı: 8
  • Basım Tarihi: 1998
  • Doi Numarası: 10.1039/a802576b
  • Dergi Adı: JOURNAL OF MATERIALS CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1835-1838
  • İnönü Üniversitesi Adresli: Evet

Özet

Methods of synthesizing materials for catalysis were developed by synthesizing eta-arene complexes of ruthenium(II) coordinated to vinylpyridine that was followed by sol-gel polymerization with 3-methacryloxypropyltriethoxysilane. To enforce sufficient catalytic properties, a series of hybrid materials from Si, Zr, Ti and Al alkoxides were prepared by co-condensation. The hydrolysis and polycondensation of materials were performed at different experimental conditions. The monomeric compounds were identified and catalytic activities were tested for cyclization of (Z)-3-methylpent-2-en-4-yn-1-ol to 2,3-dimethylfuran.