New Bisbenzimidazolin-2-Ylidene Salts as N-Heterocyclic Dicarbene Precursors: Synthesis, Characterization, and Involvement in Palladium-Catalyzed Suzuki Reactions


Yasar S., Cekirdek S., ÖZDEMİR İ.

HETEROATOM CHEMISTRY, vol.25, no.3, pp.157-162, 2014 (Peer-Reviewed Journal) identifier identifier

  • Publication Type: Article / Article
  • Volume: 25 Issue: 3
  • Publication Date: 2014
  • Doi Number: 10.1002/hc.21147
  • Journal Name: HETEROATOM CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded, Scopus
  • Page Numbers: pp.157-162

Abstract

The present work focuses on the study of catalytic activity of polystyrene-supported p-toluenesulfonic acid (PS/PTSA) and the synthesis of alpha-aminophosphonates from the Kabachnik-Fields (KF) reaction under microwave irradiation in solvent-free conditions. Recently, the catalytic activity of PS/PTSA was tested with good yields. This procedure is the simplest, most straightforward, environment friendly method for the synthesis of alpha-aminophosphonates from simple to different substituted aldehyde substrates. Furthermore, this catalyst can be recovered and reused without loss of its catalytic activity.