Synthesis of phenoxy-substituted spiro-ansa phosphazene derivatives

Begec S.

HETEROATOM CHEMISTRY, vol.18, no.4, pp.372-375, 2007 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 18 Issue: 4
  • Publication Date: 2007
  • Doi Number: 10.1002/hc.20322
  • Journal Name: HETEROATOM CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.372-375
  • Inonu University Affiliated: Yes

Abstract

In this study, reactions of 2,4,4,6,6-pentachloro-2-(2,4,6-trimethylphenoxy)cyclo-2 lambda(5), 4 lambda(5), 6 lambda(5)-triphosphazatriene (1) and 2,4,4,6,6-pentachloro-2- (2,4,6-tritertbutylphenoxy)cyclo-2 lambda(5), 4 lambda(5), 6 lambda(5)-triphosphazatriene (2) with 2,2'-dihydroxybiphenyl (3) in acetone in the presence of potassium carbonate have been investigated. Mono ansa (4) and spiro-ansa (5) derivatives were obtained from of 3 with 1, while mono spiro (6) and mono ansa (7) derivatives were obtained from 2. (c) 2007 Wiley Periodicals, Inc.