RHODIUM(I)-N-HETEROCYCLIC CARBENE-CATALYZED ADDITION OF SODIUM TETRAPHENYLBORATE TO KETONES TO FORM TERTIARY ALCOHOLS
HETEROCYCLES, cilt.89, sa.11, ss.2562-2571, 2014 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 89 Sayı: 11
- Basım Tarihi: 2014
- Doi Numarası: 10.3987/com-14-13092
- Dergi Adı: HETEROCYCLES
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.2562-2571
- İnönü Üniversitesi Adresli: Evet
Özet
Rhodium complexes ([Rh(COD)(NHC)Cl]) were synthesized by the reaction of bis(1,3-dialkylperhydrobenzimidazolin-2-ylidene) with [RhClCOD](2) in toluene and characterized by elemental analysis, H-1 NMR, C-13 NMR and IR spectroscopy. These complexes were used as catalysts for the addition of sodium tetraphenylborate to aromatic ketones and corresponding tertiary alcohols were obtained in good yields.