RHODIUM(I)-N-HETEROCYCLIC CARBENE-CATALYZED ADDITION OF SODIUM TETRAPHENYLBORATE TO KETONES TO FORM TERTIARY ALCOHOLS

Yigit B., Yigit M., ÖZDEMİR İ.

HETEROCYCLES, cilt.89, sa.11, ss.2562-2571, 2014 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 89 Sayı: 11
  • Basım Tarihi: 2014
  • Doi Numarası: 10.3987/com-14-13092
  • Dergi Adı: HETEROCYCLES
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.2562-2571
  • İnönü Üniversitesi Adresli: Evet

Özet

Rhodium complexes ([Rh(COD)(NHC)Cl]) were synthesized by the reaction of bis(1,3-dialkylperhydrobenzimidazolin-2-ylidene) with [RhClCOD](2) in toluene and characterized by elemental analysis, H-1 NMR, C-13 NMR and IR spectroscopy. These complexes were used as catalysts for the addition of sodium tetraphenylborate to aromatic ketones and corresponding tertiary alcohols were obtained in good yields.