Magnetic behavior of trinuclear vanadium(II)-diamine complexes. Part 2. Large intramolecular antiferromagnetic exchange interactions in a triangular unit


Bayri A. , Sulu M.

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, cilt.16, ss.185-188, 2006 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 16 Konu: 2
  • Basım Tarihi: 2006
  • Doi Numarası: 10.1007/s10904-006-9036-9
  • Dergi Adı: JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
  • Sayfa Sayıları: ss.185-188

Özet

This study reports the magnetic structures of newly reported trinuclear vanadium(II)-diamine complexes. Using the isotropic Heisenberg exchange Hamiltonian, it is suggested that there are strong intramolecular antiferromagnetic interactions among the vanadium(II) ions. It is also suggested that these complexes are good candidates to the geometrically frustrated systems.