2-Hydroxyethyl-Substituted (NHC)Pd(II)PPh3 Complexes: Synthesis, Characterization, Crystal Structure and Its Application on Sonogashira Cross-Coupling Reactions in Aqueous Media

AKTAŞ A., CELEPCİ D. B., GÖK Y., AYGÜN M.

CHEMISTRYSELECT, cilt.3, sa.39, ss.10932-10937, 2018 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 3 Sayı: 39
  • Basım Tarihi: 2018
  • Doi Numarası: 10.1002/slct.201802519
  • Dergi Adı: CHEMISTRYSELECT
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.10932-10937
  • Anahtar Kelimeler: Crystal structure, N-Heterocyclic carbenes, Palladium complex, Sonogashira reactions, Triphenylphosphine, HETEROCYCLIC CARBENE COMPLEXES, PALLADIUM COMPLEXES, CATALYTIC APPLICATIONS, ORGANIC-SYNTHESIS, SUZUKI-MIYAURA, COPPER FREE, LIGANDS, TRIPHENYLPHOSPHINE, PHOSPHINES, CHEMISTRY
  • İnönü Üniversitesi Adresli: Evet

Özet

This study contains the synthesis of the novel series of the 2- hydroxyethyl substituted Pd-based N-heterocyclic carbene (NHC) / triphenylphosphine (PPh3) complexes. The (NHC)Pd(II)PPh3 complexes have been prepared from the PPh3 ligand, replaced by 3-chloro pyridine ligand in (NHC)Pd(II)(3-Cl-pyridine) complexes. The novel 2-hydroxyethyl substituted (NHC)Pd(II)PPh3 complexes have been characterized by using (HNMR)-H-1, C-13 {H-1}NMR, P-31 {H-1}NMR, FTIR spectroscopy, and elemental analysis techniques. Molecular and crystal structure of 1f was obtained by using single-crystal X-ray diffraction method. The novel 2-hydroxyethyl substituted (NHC)Pd(II)PPh3 complexes have been examined as catalysts in the Sonogashira cross-coupling reactions aqueous medium and demonstrated excellent activity in this reaction.