The reactions of phenoxy substituted phosphazenes with 1,3-propanediol and 3-amino-1-propanol


Begec S., Alatas S., Kilic A.

HETEROCYCLES, cilt.71, sa.2, ss.281-287, 2007 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 71 Sayı: 2
  • Basım Tarihi: 2007
  • Doi Numarası: 10.3987/com-06-10915
  • Dergi Adı: HETEROCYCLES
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.281-287
  • İnönü Üniversitesi Adresli: Evet

Özet

In the present work, two phenoxy substituted phosphazene derivatives, 2-(2,4,6-tri-tert-butylphenoxo)-2,4,4,6,6-pentachlorocyclo-2 lambda(5), 4 lambda(5), 6 lambda(5)-triphosphazatriene (1) and 2-(2,4,6-tri-methylphenoxo)-2,4,4,6,6-pentachlorocyclo-2 lambda(5), 4 lambda(5), 6 lambda(5)-triphosphazatriene, were prepared. The reactions of these derivatives with 3-amino-1-propanol (3) and 1,3-propanediol (4) were studied. Novel phenoxy-substituted; two mono spiro (5, 8), and two dispiro phosphazene derivatives (6, 7) were synthesized. The structures of the compounds were defined by elemental analysis, IR, H-1 and P-31 NMR spectroscopy.