In situ preparation of palladium N-heterocyclic carbene complexes and use for Suzuki reaction


Ozdemir I., Gok Y., Gurbuz N., CETINKAYA E., CETINKAYA B.

JOURNAL OF HETEROCYCLIC CHEMISTRY, vol.42, no.2, pp.303-306, 2005 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 42 Issue: 2
  • Publication Date: 2005
  • Doi Number: 10.1002/jhet.5570420221
  • Journal Name: JOURNAL OF HETEROCYCLIC CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.303-306
  • Inonu University Affiliated: Yes

Abstract

The in situ prepared three component system Pd(OAc)(2), 1,3-dialkylbenzimidazolium halides (1a-e) and t-BuOK catalyses quantitatively the Suzuki cross-coupling of deactivated aryl chloride substrates. 1,3-Dialkylbenzimidazolium salts (1a-e) were characterized by conventional spectroscopic methods and elemental analyses.