INORGANICA CHIMICA ACTA, vol.471, pp.735-740, 2018 (SCI-Expanded)
Article / Article
INORGANICA CHIMICA ACTA
Science Citation Index Expanded (SCI-EXPANDED), Scopus
N-Heterocyclic carbenes, Bis(NHC)-Pd(II) complexes, Direct arylation, Butylfuran, Butylthiophene 2-Isopropylthiazole, N-HETEROCYCLIC CARBENES, PEPPSI PD-NHC, ORGANOMETALLIC CHEMISTRY, AQUEOUS-MEDIA, MIZOROKI-HECK, LIGANDS
Inonu University Affiliated:
This study contains the synthesis of the new 4-vinylbenzyl substituted bis(NHC)-Pd(II) complexes and their catalytic activity in direct arylation reaction. The bis(NHC)-Pd(II) complexes have been prepared from Ag(I) NHC complexes by transmetallation method. The complexes have been characterized by using H-1 NMR, C-13 NMR, FTIR spectroscopy and elemental analysis techniques. Also, all the complexes showed excellent activity as catalysts in the direct arylation reaction. (C) 2017 Elsevier B.V. All rights reserved.