In situ generated palladium catalysts bearing 1,3-dialkylperimidin-2-yline ligands for Suzuki reactions of aryl chlorides


Ozdemir I., Alici B., Gurbuz N., CETINKAYA E., CETINKAYA B.

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, cilt.217, ss.37-40, 2004 (SCI-Expanded) identifier identifier

Özet

Four new 1,3-dialkylperimidinium halides have been prepared and characterized. The in situ prepared three component system Pd(OAc)(2)/1,3-dialkylperimidinium (1a-d) and Cs2CO3 catalyses the Suzuki cross-coupling of deactivated aryl chloride substrates in excellent yields under mild conditions. (C) 2004 Elsevier B.V. All rights reserved.