In situ generated 1-alkylbenzimidazole-palladium catalyst for the Suzuki coupling of aryl chlorides


Ozdemir I., SAHIN N., GOK Y., DEMIR S., CETINKAYA B.

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, vol.234, no.1-2, pp.181-185, 2005 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 234 Issue: 1-2
  • Publication Date: 2005
  • Doi Number: 10.1016/j.molcata.2005.02.031
  • Journal Name: JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED)
  • Page Numbers: pp.181-185
  • Keywords: palladium, benzimidazole ligands, C-C coupling, Suzuki reaction, PALLADIUM CATALYSTS, MIYAURA REACTION, C-C, COMPLEXES, LIGANDS, AMINATION, BROMIDES, HECK, DERIVATIVES, CHEMISTRY
  • Inonu University Affiliated: Yes

Abstract

Six 1-alkylbenzimidazole have been prepared and characterized by conventional spectroscopic methods and elemental analyses. Novel in situ generated palladium-benzimidazole complexes, tested in the Suzuki coupling reaction between phenylboronic acid and several aryl chlorides showed excellent catalytic activity. (c) 2005 Elsevier B.V. All rights reserved.