Synthesis of Pd(II) 1-alkylperimidine complexes as efficient catalysts for Suzuki reactions involving arylchlorides

Ozdemir I., Alici B., Gurbuz N., CETINKAYA B., CETINKAYA E.

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, cilt.31, sa.2, ss.142-145, 2005 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 31 Sayı: 2
  • Basım Tarihi: 2005
  • Dergi Adı: RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.142-145
  • İnönü Üniversitesi Adresli: Evet

Özet

Three palladium(II) complexes of the type [PdCl2(PPh3)L] (L-1-alkylperimidine) have been prepared by reactions of [PdCl2(PR3)]2 with 1-alkylperimidine. The complexes were characterized by conventional spectroscopic methods and elemental analyses. The incorporation of N-coordinated perimidine complexes of palladium(II) gave high catalytic activity in the Suzuki coupling deactivated aryl chloride substrates.