INTERMOLECULAR HYDROAMINATION OF STYRENE CATALYZED BY PALLADIUM(II) N-HETEROCYCLIC CARBENE COMPLEXES IN IONIC LIQUID


YİĞİT B., YİĞİT M., GÖK Y., Celikal O. O.

HETEROCYCLES, vol.92, no.11, pp.1994-2003, 2016 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 92 Issue: 11
  • Publication Date: 2016
  • Doi Number: 10.3987/com-16-13546
  • Journal Name: HETEROCYCLES
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.1994-2003
  • Inonu University Affiliated: Yes

Abstract

PdCl2(NHC)(2) complexes have been synthesized by the reaction of palladium acetate with a series of benzimidazolium and imidazolinium salts and characterized by elemental analysis, H-1 NMR and C-13 NMR spectroscopy. These complexes were used as catalysts for the intermolecular hydroamination reactions between styrene with various anilines in ionic liquid at 160 degrees C and corresponding anti-Markovnikov products were obtained with a selectivity of 100% in good yields.