Synthesis, Characterization and Catalytic Activity of New N-Heterocyclic Bis(carbene)ruthenium Complexes

ÖZDEMİR İ., Demir S., GÜRBÜZ N., Cetinkaya B., TOUPET L., BRUNEAU C., ...Daha Fazla

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, sa.13, ss.1942-1949, 2009 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Basım Tarihi: 2009
  • Doi Numarası: 10.1002/ejic.200801189
  • Dergi Adı: EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Index Chemicus (IC)
  • Sayfa Sayıları: ss.1942-1949
  • Anahtar Kelimeler: Ruthenium, Carbenes, Bis(imidazolinium) salts, N ligands, C-H activation, C-H ACTIVATION, OLEFIN METATHESIS CATALYSTS, METAL-CARBENE COMPLEXES, ELECTRON-RICH OLEFINS, RUTHENIUM COMPLEXES, DIRECT ARYLATION, ARYL BROMIDES, COUPLING REACTIONS, ALKENE METATHESIS, BOND ACTIVATION
  • İnönü Üniversitesi Adresli: Evet

Özet

The reaction of RuCl2(PPh3)(3) with tBuOK-deprotonated ortho-xylyl-bis(N-imidazolinium) salts 1a-d yields RuCl2(PPh3)[bis(imidazolidin-2-ylidene)] complexes (2a-d). Under similar conditions, [RuCl2(p-cymene)](2) leads to the ruthenium complex 3 containing a tridentate eta(6)-arene-dicarbene ligand. All synthesized compounds were characterized by elemental analysis and NMR spectroscopy, and the molecular structures of 2a, 2b and 3 were determined by X-ray crystallography. The catalytic activity of RuCl2(PPh3)[bis(imidazolidin-2-ylidene)] complexes 2a-b was evaluated in the direct arylation of 2-phenylpyridine with chlorobenzene derivatives. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)