Synthesis and Characterization of the p-Fluorobenzyl Substituted Ru(II)NHC Complexes

Demirci Ö., Aktaş A., Gök Y.

3st International Conference on Physical Chemistry & Functional Materials (PCFM20), Malatya, Türkiye, 22 - 24 Eylül 2020, ss.4

  • Yayın Türü: Bildiri / Özet Bildiri
  • Basıldığı Şehir: Malatya
  • Basıldığı Ülke: Türkiye
  • Sayfa Sayıları: ss.4
  • İnönü Üniversitesi Adresli: Evet

Özet

In recent years, the coordination chemistry of N-heterocyclic carbene (NHC) ligands has drawn much attention [1,2]. In general, NHCs that form stable bonds with different metals and particularly with transition metals are considered to be an alternative for tertiary phosphines. Transition metal–NHC complexes show interesting electronic properties such as high σ-basicity and low π-acidity. Furthermore, by tuning the steric and electronic properties of the NHC, the activity and selectivity of metal–NHC complexes can be easily varied [3-5]. 

This study contains synthesis of the p-fluoro-substituted Ru(II)NHC complexes. These complexes were prepared from Ag(I)NHC complexes by transmetallation. All complexes have been fully characterized by spectroscopic techniques (1H NMR, 13C NMR, FTIR) and elemental analyses.